An intermediate-level introduction to the fundamental physical chemistry and physics of polymeric systems. The focus is entirely on equilibrium phenomena: structure and properties of polymer solutions, dense liquids, gels and rubber networks, mixtures, surfaces and interfaces, confined polymers, and biopolymers. For a detailed list of topics see Course Coverage.
MSE 401 – Thermodynamics of Materials or a 300-level course in thermo, statistical thermodynamics, or physical chemistry
Time: 2:00 – 3:20 pm onTuesdays and Thursdays, for a detailed schedule see Class Schedule.
Sections: A3 (CRN-38260) – UG, 3 credit hours and A4 (CRN-38261) – Grad, 3 or 4 credit hours
Enrolled students will receive an email with links to Campuswire and Gradescope in the first week of class.
This class is completely online and utilizes Campuswire for communications and Gradescope for assignments. The course is divided by week and there are assignments and activities to be completed each week, including homework, watching/listening to lectures, quizzes, videos, and discussions. The class is designed to be interactive and your active participation is required.
Each week, there will be a set of short lecture videos for each sub-topic as well as synchronous live sessions. The synchronous live sessions via Campuswire on Tuesdays and Thursdays will be approx. 30-45 minutes long and will contain example calculations similar to the homework problems, discussions of past homework problems, discussions of lecture material, any questions raised during the week, and/or review of essential topics. If Campuswire is not working or turns out to be unstable/inconvenient/lacking functions we will use Zoom as backup option. Students are encouraged to watch the short lecture videos, read the corresponding chapters in R&C, and familiarize themselves with the current homework problem set before the corresponding synchronous session.
During our synchronous Campuswire live sessions on Tuesdays and Thursdays, I encourage you to use your webcam so we can see your face and connect with one another. If you have a question or want to participate in a discussion, you can use the chat feature to type your question or ask it verbally during the discussion. When you are not speaking, please keep your microphone on mute in order to minimize background noise and distractions. Disruptive behavior will not be tolerated. To respect the privacy of everyone, the live sessions will not be recorded, but the notes will be made available.
All class communications and interactions with other students, TAs, Graders, and me should follow common social standards for respect and courtesy; rude, abusive, or discriminatory language will not be tolerated. I will communicate with students using Campuswire and your Illinois email account; please check both regularly. Students can expect graded work to be returned within 10 days and questions will be answered as quickly as possible. Campuswire is the best way to communicate, but I am also available via email and Zoom (during office hours/class time or a 1:1 meeting scheduled in advance).
Rubinstein and R.H. Colby, Polymer Physics (Oxford University Press, 2003, any edition)
Additional texts of interest are listed here.
*R&C – M. Rubinstein and R.H. Colby, Polymer Physics (Oxford University Press, 2003)
*B&T – C. Branden & J. Tooze, Introduction to Protein Structure (Garland, 1999)
I. Polymer Structure & Ideal Chain Statistics (R&C §1, 2)
Macromolecular structure; fractal nature of polymer conformations; molar mass distributions; chain flexibility; ideal chain models; persistence length; radius of gyration; end-to-end vectors; conformational statistics; elementary statistical mechanics; ideal chain free energy; scaling arguments; coarse graining; pair correlation functions;
II. Dilute Solutions & Real Chain Statistics (R&C §3, 5.5-5.6)
Monomer-monomer interactions; excluded volume; solvent quality; Flory theory; polymer deformation; temperature effects; role of spatial dimension; polymer collapse; three-body effects; virial expansion; tethered polymer brushes; chain adsorption and confinement.
III. Liquid-Liquid Phase Separation (R&C §4)
Energy and entropy of mixing; mean field binary mixture theory – regular solution theory, polymer solutions, polymer blends; Flory interaction parameter; stability conditions; metastability, binodals, and spinodals; phase diagrams; lever rule; osmotic pressure; temperature-induced phase separation.
IV. Dense Solutions & Melts (R&C §5.1-5.4, 5.7)
Dilute, semi-dilute, and concentrated regimes; theta, poor and good solvents; scaling concepts; osmotic pressure; correlation length.
V. Rubber Networks & Chemical Gelation (R&C §6, 7.1-7.2)
Sol-gel model; random branching; percolation transition; crosslinking; hyperbranching and dendrimers; mean field gelation; scaling, hyperscaling, and universality; rubber thermodynamics; affine network model; phantom network model.
VI. Polymer Physics at U of I
Discussion of ongoing research topics in different groups on Campus and how their research relates to the course content.
Twelve (12) homework assignments for this class will be issued via Gradescope for each week (see Class Schedule.). Students will have one week to complete the assignment and they are to be submitted on Gradescope, usually on Tuesdays 6pm CT.
Late work up to 24 hours will be accepted three times. Students with valid reasons precluding on-time submission beyond that should contact Prof. Statt well in advance of the deadline. Students are strongly encouraged to complete all assignments to assess their own understanding of the course material. It is acceptable to work with fellow students on homework problems, and to ask as well as answer questions pertaining homework online on Campuswire. Provision will be made for office hours during which to discuss the problems and solutions. Exam questions will be loosely based on assigned homework problems.
Twelve (12) short online multiple-choice quizzes will be issued via Gradescope each week (see Class Schedule), usually due on Tuesdays 6pm CT, to gauge elementary understanding and mastery of the course material. Each quiz has a time limit of 60 minutes.
There will be one (1) midterm exam, and one (1) final exam. Both exams will be issued and submitted via Gradescope, specific details will be made available a week before each exam. We will not utilize any proctoring service, but instead rely on the academic integrity and responsibility of each student. Both exams will be closed book, but students will be permitted to use a calculator and a single, double-sided, letter-sized sheet of handwritten notes. Resources outside of this (including fellow students, textbooks, lecture notes, and online resources) are explicitly not permitted. The midterm will take place during scheduled class time, the final during the university final exam period (see Class Schedule). Efforts will be made to schedule exams to minimize scheduling conflicts, but the responsibility lies with the student to anticipate and resolve scheduling conflicts with Prof. Statt well in advance of the exam dates.
Paper (4-credit option only)
Students in the 4-credit option will write a term paper on a student-selected topic in polymer physics. The term paper should be written in the style of a literature review or summary of a relevant research topic. Students with valid reasons precluding on-time submission should contact Prof. Statt well in advance of the deadline. The due dates are listed in the Class Schedule.
Topic: Term paper topic selections are due via Gradescope. Submissions should take the form of a one-sentence topic title and short (≤250 word) abstract summarizing the topic and projected thrusts of the paper. Prof. Statt will be available to discuss and advise topic choice and general direction of the paper, overlap with relevant research projects of the student in the area of polymers are encouraged. Early topic identification and submission is also encouraged.
Paper: Both first draft and final version of the term papers are due via Gradescope. Papers should be 5-6 pages in length (excl. figures and bibliography; 12-pt font, 1-inch margins, single-spaced). Students will research and summarize the state of the field, reference classic texts and papers, and identify the principal challenges, important questions, and current research directions in the field. Prof. Statt will be available to discuss and advise paper research and production. Papers will be graded on: (i) topic definition and motivation (10%), (ii) summary of status of field (20%), (iii) identification and motivation of open challenges (25%), (iv) analysis of current research into identified challenge (20%), (v) clarity of report (10%), (vi) appropriate citations and formatted bibliography (5%).
Peer review: Reviews are due via Gradescope. Each submitted paper will be assigned to two other randomly selected students in the class for peer review. Each student will write a short (≤1 page) constructive review on their assigned papers, summarizing the content of the paper very briefly, and giving feedback on (i) topic, (ii) summary of the field, (iii) open challenges, (iv) analysis, (v) clarity of the term paper, as well as formatting/style. The remaining 10% of the grade will be the quality of the given peer review. Each student will receive the peer reviews on their paper, will incorporate the feedback and submit a final version via Gradescope.
Each student is responsible for submitting their own original quiz responses, homework assignments, and (if applicable) term paper. Collaborative interaction is permissible and encouraged via Campuswire, but each student must perform all calculations themselves, and submit their own work. Plagiarism will not be tolerated, and verified incidents will result in all parties receiving a zero on their project and formal academic sanctions. Students are responsible for familiarizing themselves with the definition and penalties for plagiarism detailed in Section I-401 of the UIUC Student Code. Ignorance of these policies is not an excuse for any academic dishonesty. As a student it is your responsibility to refrain from infractions of academic integrity and from conduct that aids others in such infractions. A short guide to academic integrity issues may be found here. Do not hesitate to ask the instructor(s) if you are ever in doubt about what constitutes plagiarism, cheating, or any other breach of academic integrity. Note that the code’s definition of plagiarism includes “copying another student’s paper or working with another person when both submit similar papers without authorization to satisfy an individual assignment”.
Please note that all course materials are protected by copyright and are considered intellectual property. Course materials should only be used for this course and should not be shared with anyone not in the course, including uploading to a study site, social media, or other online sharing mechanism.
|A3/A4 (3-credits):||A4 (4-credits):|
Participation includes class attendance, and/or participating in discussions & questions during class, watching class videos, posting content questions on Campuswire, and answering content questions on Campuswire. International students in significantly different timezones will be able to gain their participation points by posting and answering questions on Campuswire.
Letter grades will be based on final aggregate student scores, with numerical cutoffs specified by the instructor. However, students with aggregate scores >95% are guaranteed at least an A, >85% at least a B, and >75% at least a C (i.e. cutoffs will not be higher than these values).
Tentative Class Schedule
|Class||Date||Day||Lecture Topic||HW, Quiz & Paper|
|1||Jan 26||Tu||Course Introduction
I. Polymer Structure & Ideal Chain Statistics
|2||Jan 28||T||I. Polymer Structure & Ideal Chain Statistics|
|3||Feb 2||Tu||I. Polymer Structure & Ideal Chain Statistics||HW #1 & Quiz #1 due|
|4||Feb 4||T||I. Polymer Structure & Ideal Chain Statistics|
|5||Feb 9||Tu||I. Polymer Structure & Ideal Chain Statistics||HW #2 & Quiz #2 due|
|6||Feb 11||T||I. Polymer Structure & Ideal Chain Statistics|
|7||Feb 16||Tu||II. Dilute Solutions & Real Chain Statistics||HW #3 & Quiz #3 due,Paper topics due, 6pm CT|
|8||Feb 18||T||II. Dilute Solutions & Real Chain Statistics|
|9||Feb 23||Tu||II. Dilute Solutions & Real Chain Statistics||HW #4 due & Quiz #4 due|
|10||Feb 25||T||II. Dilute Solutions & Real Chain Statistics|
|11||Mar 2||Tu||II. Dilute Solutions & Real Chain Statistics||HW #5 & Quiz #5 due|
|12||Mar 4||T||III. Liquid-Liquid Phase Separation|
|13||Mar 9||Tu||III. Liquid-Liquid Phase Separation||HW #6 & Quiz #6 due|
|14||Mar 11||T||III. Liquid-Liquid Phase Separation||Paper draft due, 6pm CT|
|15||Mar 16||Tu||III. Liquid-Liquid Phase Separation||HW #7 & Quiz #7 due|
|16||Mar 18||T||Midterm Review|
|17||Mar 23||Tu||MIDTERM EXAM|
|18||Mar 25||T||IV. Dense Solutions & Melts|
|19||Mar 30||Tu||IV. Dense Solutions & Melts||HW #8 & Quiz #8 due|
|20||Apr 1||T||IV. Dense Solutions & Melts||Paper reviews due, 6pm CT|
|21||Apr 6||Tu||V. Rubber Networks & Chemical Gelation||HW #9 & Quiz #9 due|
|22||Apr 8||T||V. Rubber Networks & Chemical Gelation|
|24||Apr 15||T||V. Rubber Networks & Chemical Gelation||HW #10 & Quiz #10 due|
|25||Apr 20||Tu||V. Rubber Networks & Chemical Gelation|
|26||Apr 22||T||V. Rubber Networks & Chemical Gelation||HW #11 & Quiz #11 due|
|27||Apr 27||Tu||VI. Polymer Physics at U of I||Final paper due, 6pm CT|
|28||Apr 29||T||VI. Polymer Physics at U of I||HW #12 & Quiz #12 due|
|May 4||Tu||Final Review|
|May 7-14||FINAL EXAM|
P.C. Hiemenz, Polymer Chemistry (CRC Press, 1984)
P.-G. de Gennes, Scaling Concepts in Polymer Physics (Cornell University Press, 1979)
A.Y. Grosberg & A.R. Khoklov, Statistical Physics of Macromolecules (AIP, 2002)
Strobl, The Physics of Polymers (Springer, 2010)
A.Y. Grosberg & A.R. Khoklov, Giant Molecules (World Scientific Publishing, 2010)
U.W. Gedde, Polymer Physics (Springer, 1995)
Doi & S.F. Edwards, The Theory of Polymer Dynamics (Oxford University Press, 1988)
P.J. Flory, Statistical Mechanics of Chain Molecules (Oxford University Press, 1989)
P.J. Flory, Principles of Polymer Chemistry (Cornell University Press, 1953)
Branden & J. Tooze, Introduction to Protein Structure (Garland, 1999)
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